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"silicon" Deutsch ÜbersetzungÜbersetzung im Kontext von „silicon“ in Englisch-Deutsch von Reverso Context: silicon carbide, silicon nitride, silicon dioxide, silicon oxide, silicon substrate. Übersetzung von silicon – Englisch–Deutsch Wörterbuch. silicon. noun. /ˈsilikən/. ○ chemistry. (symbol Si) a chemical element with. Lernen Sie die Übersetzung für 'silicon' in LEOs Englisch ⇔ Deutsch Wörterbuch. Mit Flexionstabellen der verschiedenen Fälle und Zeiten ✓ Aussprache und.
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English I went into a clean room with a fresh silicon wafer, and then I just cranked away at all the big machines for about hours.
Collocations "silicone gel" in German. Synonyms Synonyms English for "silicon":. English atomic number 14 Si. English silicone polymer.
English chip micro chip microchip microprocessor chip. More by bab. English silicate minerals silicate particles silicates siliceous siliceous earth silicic silicic acid silicification silicified silicious silicon silicon atoms silicon based silicon breast implant silicon breasts silicon carbide silicon cells silicon chip silicon computer silicon crystal silicon device Do you want to translate into other languages?
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Top Job Roles. Silicon carbide SiC was first made by Edward Goodrich Acheson in , who named it carborundum to reference its intermediate hardness and abrasive power between diamond an allotrope of carbon and corundum aluminium oxide.
He soon founded a company to manufacture it, and today about one million tonnes are produced each year. They are variations of the same chemical compound that are identical in two dimensions and differ in the third.
Thus they can be viewed as layers stacked in a certain sequence. It is resistant to most aqueous acids, phosphoric acid being an exception. It is mostly used as an abrasive and a refractory material, as it is chemically stable and very strong, and it fractures to form a very sharp cutting edge.
It is also useful as an intrinsic semiconductor, as well as an extrinsic semiconductor upon being doped. Because the Si—C bond is close in strength to the C—C bond, organosilicon compounds tend to be markedly thermally and chemically stable.
Furthermore, since carbon and silicon are chemical congeners, organosilicon chemistry shows some significant similarities with carbon chemistry, for example in the propensity of such compounds for catenation and forming multiple bonds.
Thus the Si—F bond is significantly stronger than even the C—F bond and is one of the strongest single bonds, while the Si—H bond is much weaker than the C—H bond and is readily broken.
Furthermore, the ability of silicon to expand its octet is not shared by carbon, and hence some organosilicon reactions have no organic analogues.
For example, nucleophilic attack on silicon does not proceed by the S N 2 or S N 1 processes, but instead goes through a negatively charged true pentacoordinate intermediate and appears like a substitution at a hindered tertiary atom.
Nevertheless, despite these differences, the mechanism is still often called "S N 2 at silicon" for simplicity. One of the most useful silicon-containing groups is trimethylsilyl , Me 3 Si—.
The Si—C bond connecting it to the rest of the molecule is reasonably strong, allowing it to remain while the rest of the molecule undergoes reactions, but is not so strong that it cannot be removed specifically when needed, for example by the fluoride ion, which is a very weak nucleophile for carbon compounds but a very strong one for organosilicon compounds.
It may be compared to acidic protons ; while trisilylmethyl is removed by hard nucleophiles instead of bases, both removals usually promote elimination.
As a general rule, while saturated carbon is best attacked by nucleophiles that are neutral compounds, those based on nonmetals far down on the periodic table e.
For example, enolates react at the carbon in haloalkanes , but at the oxygen in silyl chlorides; and when trimethylsilyl is removed from an organic molecule using hydroxide as a nucleophile, the product of the reaction is not the silanol as one would expect from using carbon chemistry as an analogy, because the siloxide is strongly nucleophilic and attacks the original molecule to yield the silyl ether hexamethyldisiloxane , Me 3 Si 2 O.
Thus, for example, the silyl triflates are so electrophilic that they react 10 8 to 10 9 times faster than silyl chlorides with oxygen-containing nucleophiles.
Trimethylsilyl triflate is in particular a very good Lewis acid and is used to convert carbonyl compounds to acetals and silyl enol ethers , reacting them together analogously to the aldol reaction.
Si—C bonds are commonly formed in three ways. The second route has the drawback of not being applicable to the most important silanes, the methyl and phenyl silanes.
Standard organic reactions suffice to produce many derivatives; the resulting organosilanes are often significantly more reactive than their carbon congeners, readily undergoing hydrolysis, ammonolysis, alcoholysis, and condensation to form cyclic oligomers or linear polymers.
The word "silicone" was first used by Frederic Kipping in He invented the word to illustrate the similarity of chemical formulae between Ph 2 SiO and benzophenone , Ph 2 CO, although he also stressed the lack of chemical resemblance due to the polymeric structure of Ph 2 SiO, which is not shared by Ph 2 CO.
Furthermore, they are resistant over long periods of time to ultraviolet radiation and weathering, and are inert physiologically.
They are fairly unreactive, but do react with concentrated solutions bearing the hydroxide ion and fluorinating agents, and occasionally, may even be used as mild reagents for selective syntheses.
In the universe, silicon is the seventh most abundant element, coming after hydrogen , helium , carbon , nitrogen , oxygen , and neon.
These abundances are not replicated well on Earth due to substantial separation of the elements taking place during the formation of the Solar System.
Silicon makes up Further fractionation took place in the formation of the Earth by planetary differentiation : Earth's core , which makes up The crystallisation of igneous rocks from magma depends on a number of factors; among them are the chemical composition of the magma, the cooling rate, and some properties of the individual minerals to be formed, such as lattice energy , melting point, and complexity of their crystal structure.
As magma is cooled, olivine appears first, followed by pyroxene , amphibole , biotite mica, orthoclase feldspar , muscovite mica , quartz , zeolites , and finally, hydrothermal minerals.
This sequence shows a trend toward increasingly complex silicate units with cooling, and the introduction of hydroxide and fluoride anions in addition to oxides.
Many metals may substitute for silicon. After these igneous rocks undergo weathering , transport, and deposition, sedimentary rocks like clay, shale, and sandstone are formed.
Metamorphism also may occur at high temperatures and pressures, creating an even vaster variety of minerals.
There are four sources for silicon fluxes into the ocean include chemical weathering of continental rocks, river transport, dissolution of continental terrigenous silicates, and through the reaction between submarine basalts and hydrothermal fluid which release dissolved silicon.
All four of these fluxes are interconnected in the ocean's biogeochemical cycle as they all were initially formed from the weathering of Earth's crust.
Approximately megatonnes of Aeolian dust is deposited into the world's oceans each year. Of that value, megatonnes are in the form of particulate silicon.
The total amount of particulate silicon deposition into the ocean is still less than the amount of silicon influx into the ocean via riverine transportation.
The reduction is carried out in an electric arc furnace , with an excess of SiO 2 used to stop silicon carbide SiC from accumulating: .
This reaction, known as carbothermal reduction of silicon dioxide, usually is conducted in the presence of scrap iron with low amounts of phosphorus and sulfur , producing ferrosilicon.
It is followed by Russia , t , Norway , t , Brazil , t , and the United States , t. However, even greater purity is needed for semiconductor applications, and this is produced from the reduction of tetrachlorosilane silicon tetrachloride or trichlorosilane.
The former is made by chlorinating scrap silicon and the latter is a byproduct of silicone production. These compounds are volatile and hence can be purified by repeated fractional distillation , followed by reduction to elemental silicon with very pure zinc metal as the reducing agent.
The spongy pieces of silicon thus produced are melted and then grown to form cylindrical single crystals, before being purified by zone refining.
Other routes use the thermal decomposition of silane or tetraiodosilane SiI 4. Another process used is the reduction of sodium hexafluorosilicate , a common waste product of the phosphate fertilizer industry, by metallic sodium : this is highly exothermic and hence requires no outside fuel source.
Hyperfine silicon is made at a higher purity than almost every other material: transistor production requires impurity levels in silicon crystals less than 1 part per 10 10 , and in special cases impurity levels below 1 part per 10 12 are needed and attained.
Most silicon is used industrially without being purified, and indeed, often with comparatively little processing from its natural form.
Many of these have direct commercial uses, such as clays, silica sand, and most kinds of building stone. Thus, the vast majority of uses for silicon are as structural compounds, either as the silicate minerals or silica crude silicon dioxide.
Silicates are used in making Portland cement made mostly of calcium silicates which is used in building mortar and modern stucco , but more importantly, combined with silica sand, and gravel usually containing silicate minerals such as granite , to make the concrete that is the basis of most of the very largest industrial building projects of the modern world.
Silica is used to make fire brick , a type of ceramic. Silicate minerals are also in whiteware ceramics , an important class of products usually containing various types of fired clay minerals natural aluminium phyllosilicates.
An example is porcelain , which is based on the silicate mineral kaolinite. Traditional glass silica-based soda-lime glass also functions in many of the same ways, and also is used for windows and containers.
In addition, specialty silica based glass fibers are used for optical fiber , as well as to produce fiberglass for structural support and glass wool for thermal insulation.
Silicones often are used in waterproofing treatments, molding compounds, mold- release agents , mechanical seals, high temperature greases and waxes, and caulking compounds.
Silicone is also sometimes used in breast implants , contact lenses, explosives and pyrotechnics. Silicon is a component of some superalloys.
Elemental silicon is added to molten cast iron as ferrosilicon or silicocalcium alloys to improve performance in casting thin sections and to prevent the formation of cementite where exposed to outside air.
The presence of elemental silicon in molten iron acts as a sink for oxygen, so that the steel carbon content, which must be kept within narrow limits for each type of steel, can be more closely controlled.
Silicon is an important constituent of electrical steel , modifying its resistivity and ferromagnetic properties.
The properties of silicon may be used to modify alloys with metals other than iron. This greatly reduces tearing and cracks formed from stress as casting alloys cool to solidity.
Silicon also significantly improves the hardness and thus wear-resistance of aluminium. Monocrystalline silicon of such purity is usually produced by the Czochralski process , is used to produce silicon wafers used in the semiconductor industry , in electronics, and in some high-cost and high-efficiency photovoltaic applications.
Pure silicon has too low a conductivity i. In practice, pure silicon is doped with small concentrations of certain other elements, which greatly increase its conductivity and adjust its electrical response by controlling the number and charge positive or negative of activated carriers.
Such control is necessary for transistors , solar cells , semiconductor detectors , and other semiconductor devices used in the computer industry and other technical applications.
In common integrated circuits , a wafer of monocrystalline silicon serves as a mechanical support for the circuits, which are created by doping and insulated from each other by thin layers of silicon oxide , an insulator that is easily produced on Si surfaces by processes of thermal oxidation or local oxidation LOCOS , which involve exposing the element to oxygen under the proper conditions that can be predicted by the Deal—Grove model.
Silicon has become the most popular material for both high power semiconductors and integrated circuits because it can withstand the highest temperatures and greatest electrical activity without suffering avalanche breakdown an electron avalanche is created when heat produces free electrons and holes, which in turn pass more current, which produces more heat.
In addition, the insulating oxide of silicon is not soluble in water, which gives it an advantage over germanium an element with similar properties which can also be used in semiconductor devices in certain fabrication techniques.
Monocrystalline silicon is expensive to produce, and is usually justified only in production of integrated circuits, where tiny crystal imperfections can interfere with tiny circuit paths.
For other uses, other types of pure silicon may be employed. These include hydrogenated amorphous silicon and upgraded metallurgical-grade silicon UMG-Si used in the production of low-cost, large-area electronics in applications such as liquid crystal displays and of large-area, low-cost, thin-film solar cells.
Such semiconductor grades of silicon are either slightly less pure or polycrystalline rather than monocrystalline, and are produced in comparable quantities as the monocrystalline silicon: 75, to , metric tons per year.
The market for the lesser grade is growing more quickly than for monocrystalline silicon. By , polycrystalline silicon production, used mostly in solar cells, was projected to reach , metric tons per year, while monocrystalline semiconductor grade silicon was expected to remain less than 50, tons per year.
Silicon quantum dots are created through the thermal processing of hydrogen silsesquioxane into nanocrystals ranging from a few nanometers to a few microns, displaying size dependent luminescent properties.
A benefit of using silicon based quantum dots over cadmium or indium is the non-toxic, metal-free nature of silicon. Another application of silicon quantum dots is for sensing of hazardous materials.
The sensors take advantage of the luminescent properties of the quantum dots through quenching of the photoluminescence in the presence of the hazardous substance.
The effect can also be achieved in reverse with a donor molecule having its highest occupied molecular orbital HOMO slightly higher than a valence band edge of the quantum dot, allowing electrons to transfer between them, filling the holes and preventing recombination.
Fluorescence resonance energy transfer occurs when a complex forms between the quantum dot and a quencher molecule.
The complex will continue to absorb light but when the energy is converted to the ground state it does not release a photon, quenching the material.
The third method uses different approach by measuring the photocurrent emitted by the quantum dots instead of monitoring the photoluminescent display.
If the concentration of the desired chemical increases then the photocurrent given off by the nanocrystals will change in response.
Although silicon is readily available in the form of silicates , very few organisms use it directly. Diatoms , radiolaria , and siliceous sponges use biogenic silica as a structural material for their skeletons.
In more advanced plants, the silica phytoliths opal phytoliths are rigid microscopic bodies occurring in the cell; some plants, for example rice , need silicon for their growth.
Diatoms uses silicon in the biogenic silica BSIO 2 form,  which is taken up by the silicon transport protein SIT to be predominantly used in the cell wall structure as frustules.
Silicon forms a nutrient-like profile in the ocean due to the diatom productivity in shallow depths.
Diatom productivity in the upper ocean contribute to the amount of silicon exported to the lower ocean. Marine snow involves the downward transfer of particulate organic matter by vertical mixing of dissolved organic matter.
In coastal zones, diatoms serve as the major phytoplanktonic organisms and greatly contribute to biogenic silica production. In the open ocean, however, diatoms have a reduced role in global annual silica production.
The Southern Ocean produces about one-third of global marine biogenic silica. There is some evidence that silicon is important to human health for their nail, hair, bone, and skin tissues,  for example, in studies that demonstrate that premenopausal women with higher dietary silicon intake have higher bone density , and that silicon supplementation can increase bone volume and density in patients with osteoporosis.
Silicon is currently under consideration for elevation to the status of a "plant beneficial substance by the Association of American Plant Food Control Officials AAPFCO.
People may be exposed to elemental silicon in the workplace by breathing it in, swallowing it, or having contact with the skin or eye.
In the latter two cases, silicon poses a slight hazard as an irritant. It is hazardous if inhaled. From Wikipedia, the free encyclopedia. Not to be confused with the silicon-containing synthetic polymer Silicone.
Chemical element with atomic number For other uses, see Element 14 disambiguation. Main article: Isotopes of silicon. Main articles: Silicide and Binary compounds of silicon.
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